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Beilstein J. Org. Chem. 2014, 10, 1787–1795, doi:10.3762/bjoc.10.187
Graphical Abstract
Scheme 1: Synthesis of poly(propylene carbonate) (PPC) using catalyst 1.
Scheme 2: PO/PA alternating copolymerization.
Figure 1: 1H NMR spectrum of crude products in the PO/PA alternating polymerization (A, entry 1 in Table 1), PO/CO2/...
Figure 2: GPC curves of the PO/PA copolymers.
Scheme 3: CO2/PO/PA terpolymerization.
Figure 3: DSC curves of PO/PA alternating polymer (A, entry 1 in Table 1), PO/CO2/PA terpolymer (B, entry 7 in Table 2), an...
Scheme 4: PA incorporation process in PO/CO2/PA terpolymerization.